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Introduction
Fact:
waterborne pathogenic microorganisms are a major source
of disease worldwide. Pathogens and water system deficiencies that
are identified in outbreaks may also be important causes of endemic
waterborne illness.
Of
increased importance, however, are outbreaks caused by the microbial
contamination of water distribution systems. In light of the growing
evidence showing the resistance of certain micro-organisms to
standard disinfection methods (including chlorination and UV
radiation) mechanical removal of these contaminants is often the
most reliable choice.
The NanoCeram® Advantage
The electroadsorptive ingredient in the
NanoCeram® filter is a nano alumina fiber that
has a surface area from 350-500 m2/g, with
virtually all of that on the outside surface of the fiber
and exposed to the entire spectrum of particulate in an
aqueous stream (Figure 9). Such high surface areas are
unattainable either in a membrane or in a fibrous filter
even where nanofibers are being used. Nanofibers are very
difficult to manufacture much below a 100nm diameter versus
a 2nm diameter in the case of nano alumina.
And even if a nanoalumina fiber with a 2nm diameter were
commercially available, this fiber (and
virtually every other nanomaterial) would have a very strong
tendency to agglomerate with the other nanofibers. Once this
agglomeration occurs, the advantage of that huge surface
area is lost. The key to NanoCeram®’s advantage
is that we’ve developed a novel method of grafting these
submicron alumina fibers permanently to a scaffold. This
serves to keep the fibers separate from one another so that
each fiber can do what it is optimized to do . . . attract
and capture submicron particles.
What is DHC & Why Does it Matter?
Dirt holding capacity (“DHC”) generally
refers to the capacity of a filter cartridge to retain a
given weight of particles before the cartridge plugs. Logic
dictates that for a given pore size, the larger the particle
challenging that filter, the greater would be the DHC (based
on how long it takes for that filter to plug) as smaller
particles would simply pass through the larger pores.
However, there are few applications where
capturing those smaller particles don’t have significant
value.
Much like a standard filter, the
NanoCeram® electropositive fibrous filter media
mechanically sieves particles larger than its average pore
size. However, the NanoCeram® also
adsorbs smaller particles throughout its entire
fibrous structure, resulting in DHC levels many times
greater than standard filter cartridges. In other words, if
you were to weigh the amount of “dirt” captured by a
NanoCeram filter cartridge versus other filter cartridges,
the NanoCeram filter would far outperform the standard
filter (see Figure 2).
As a “broad spectrum” particle adsorber,
the NanoCeram® cartridge removes both coarse
particulate as well as fines. For example, in applications
currently using a 3 micron cartridge, the NanoCeram®
will remove 3 micron and larger particulate with a similar
efficiency to the 3 micron sediment cartridge. Yet, when the
two cartridges are weighed and compared after operating
under identical conditions and for the same period of time,
the NanoCeram® will have removed several times
the quantity of particulate (by weight) than the standard
sediment cartridge. The difference is that NanoCeram®
will remove virtually all of the sub-micron particles that
pass through a conventional filter.
In many applications, removing sub-micron
particles is vital. They are responsible for much of the
fouling of reverse osmosis (RO) membranes, and would degrade
the efficiency of ultraviolet (UV) and ozone disinfection
systems. Unfiltered fines and colloidal matter can also
affect chemical processes and impact the quality of the
surfaces of precision products.
How Long Will My NanoCeram
Cartridge Continue to Work?
How long a filter will last is a very
common question, but a difficult one to answer. Several
factors can affect life, but the overriding factor is the
load and type of particles being filtered. Particulate
contaminants may include colloidal inert matter, inorganic
particles such as metal oxides, natural organic matter
(NOM), total organic carbon (TOC) to include humic/tannic/fulvic
acids, endotoxins, bacteria, cysts, virus, etc. New EPA (in
the United States) regulations require that the turbidity
(defined as a cloudy condition in water due to suspended
silt or organic matter) of municipal water must be reduced
to less than 1 NTU (Nephelometric Turbidity Units).
The answer is even more complex when
discussing soluble contaminants such as chlorine. In this
case, flow velocity (the speed at which water flows through
a set surface area of media, often in terms of cm/sec) is a
very important metric.
All carbon-based products require “residence time” for
contact between the contaminant and the carbon itself. The
longer the contact time, the greater the dynamic adsorption
rate of the carbon for soluble contaminants. This is why the
smaller particles of PAC used in NanoCeram-PAC filters offer
such an advantage. The huge surface area of such small
carbon particles means that available surface area to adsorb
the chlorine is enormous (more capture sites). Therefore,
the “bounce-back” capacity of the PAC allows for higher flow
rates to attain chlorine adsorption rates which would be
comparable to GAC-based filters running at much slower flow
rates.
How Do I Determine My
Filter’s Efficiency?
Although not often used in today’s world
of filtration, it is useful to offer a brief discussion of
Filtration Efficiency Percentages. Efficiency is an
indicator of how well a filter controls particulate: i.e.,
if one out of every two particles (> 0.5 μ) in the fluid
passes through the filter, the efficiency at 0.5 μ = 2; if
one out of every 200 of the particles (> 0.5 μ) passes
through the filter the efficiency = 200.
Therefore, filters with higher efficiency
retain more particles of a given particle size. Efficiency
for a given particle size is also dependent on the quantity
of the particle size in a water stream.
NanoCeram® filter cartridges
exhibit a level of unmatched efficiency given their high
flow rates and low pressure drop. This efficiency is
attributed to the strong electropositive forces that capture
particulates many times smaller than the media’s relatively
large pore size. NanoCeram®’s efficiency has been
determined through laboratory testing with a given particle
size of latex beads (typically used for filtration R & D),
their concentration (stated in NTU) in a flowing stream,
with the resulting efficiency stated as a percentage of
particles removed.
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